A primitive ocean on Mars held more water than Earth's Arctic Ocean, and covered a greater portion of the planet's surface than the Atlantic Ocean does on Earth, according to new results published this week. An international team of scientists used ESO's Very Large Telescope, along with instruments at the W. M. Keck Observatory and the NASA Infrared Telescope Facility, to monitor the atmosphere of the planet and map out the properties of the water in different parts of Mars's atmosphere over a six-year period. These new maps are the first of their kind. The results appear online in the journal Science.

About four billion years ago, the young planet would have had enough water to cover its entire surface in a liquid layer about 140 metres deep, but it is more likely that the liquid would have pooled to form an ocean occupying almost half of Mars's northern hemisphere, and in some regions reaching depths greater than 1.6 kilometres.

"Our study provides a solid estimate of how much water Mars once had, by determining how much water was lost to space," said Geronimo Villanueva, a scientist working at NASA's Goddard Space Flight Center in Greenbelt, Maryland, USA, and lead author of the new paper. "With this work, we can better understand the history of water on Mars."

The new estimate is based on detailed observations of two slightly different forms of water in Mars's atmosphere. One is the familiar form of water, made with two hydrogen atoms and one oxygen, H2O. The other is HDO, or semi-heavy water, a naturally occurring variation in which one hydrogen atom is replaced by a heavier form, called deuterium.

As the deuterated form is heavier than normal water, it is less easily lost into space through evaporation. So, the greater the water loss from the planet, the greater the ratio of HDO to H2O in the water that remains [1].

The researchers distinguished the chemical signatures of the two types of water using ESO's Very Large Telescope in Chile, along with instruments at the W. M. Keck Observatory and the NASA Infrared Telescope Facility in Hawaii [2]. By comparing the ratio of HDO to H2O, scientists can measure by how much the fraction of HDO has increased and thus determine how much water has escaped into space. This in turn allows the amount of water on Mars at earlier times to be estimated.

In the study, the team mapped the distribution of H2O and HDO repeatedly over nearly six Earth years - equal to about three Mars years - producing global snapshots of each, as well as their ratio. The maps reveal seasonal changes and microclimates, even though modern Mars is essentially a desert.

Ulli Kaeufl of ESO, who was responsible for building one of the instruments used in this study and is a co-author of the new paper, adds: "I am again overwhelmed by how much power there is in remote sensing on other planets using astronomical telescopes: we found an ancient ocean more than 100 million kilometres away!"

The team was especially interested in regions near the north and south poles, because the polar ice caps are the planet's largest known reservoir of water. The water stored there is thought to document the evolution of Mars's water from the wet Noachian period, which ended about 3.7 billion years ago, to the present.

The new results show that atmospheric water in the near-polar region was enriched in HDO by a factor of seven relative to Earth's ocean water, implying that water in Mars's permanent ice caps is enriched eight-fold. Mars must have lost a volume of water 6.5 times larger than the present polar caps to provide such a high level of enrichment. The volume of Mars's early ocean must have been at least 20 million cubic kilometres.

Based on the surface of Mars today, a likely location for this water would be the Northern Plains, which have long been considered a good candidate because of their low-lying ground. An ancient ocean there would have covered 19% of the planet's surface - by comparison, the Atlantic Ocean occupies 17% of the Earth's surface.

"With Mars losing that much water, the planet was very likely wet for a longer period of time than previously thought, suggesting the planet might have been habitable for longer," said Michael Mumma, a senior scientist at Goddard and the second author on the paper.

It is possible that Mars once had even more water, some of which may have been deposited below the surface. Because the new maps reveal microclimates and changes in the atmospheric water content over time, they may also prove to be useful in the continuing search for underground water.

This research was presented in a paper entitled "Strong water isotopic anomalies in the Martian atmosphere: probing current and ancient reservoirs", by G. VIllanueva et al., to appear online in Science on 5 March 2015. The team is composed of G.L. Villanueva (NASA Goddard Space Flight Center, Greenbelt, USA; Catholic University of America, Washington, D.C., USA), M.J. Mumma (NASA Goddard Space Flight Center), R.E. Novak (Iona College, New York, USA), H.U. Kaufl (ESO, Garching, Germany), P. Hartogh (Max Planck Institute for Solar System Research, Gottingen, Germany), T. Encrenaz (CNRS - Observatoire de Paris-Meudon, Paris, France), A. Tokunaga (University of Hawaii-Manoa, Hawaii, USA), A. Khayat (University of Hawaii-Manoa) and M. D. Smith (NASA Goddard Space Flight Center).