![]() |
![]() |
![]() |
![]() |
![]() |
![]() |
![]() |
![]() |
![]() |
![]() |
![]() by Staff Writers Washington DC (SPX) Jan 25, 2016
If you've ever experienced a bad sunburn, you know the damage that ultraviolet (UV) light can cause to living cells (like your skin). Out in space, where the level of radiation from the sun can be even higher, it can damage sensitive electronics aboard in-flight spacecraft. The dangers of UV light have prompted scientists to search for versatile materials that block UV and can withstand long radiation exposure times without falling apart. Now a group of researchers in China has developed a new method to create transparent, glass-based materials with UV-absorbing power and long lifetimes. The team demonstrated that the new glass effectively protects living cells and organic dyes, and believe it could also be developed as a transparent shield to protect electronics in space. They describe their results in Optical Materials Express, a journal of The Optical Society. The researchers used a metal oxide - cerium (IV) oxide (CeO2) - well-known for its ability to absorb UV photons to craft the composite glass-based UV absorber. Other key features of the final composite material are the optical transparency of the glass and the material's ability to suppress the separation of photo-generated electrons and holes. The later feature slows down a light-induced reaction that would lead to the ultimate breakdown of the material under prolonged exposure to UV radiation. The method the team developed is based on the self-limited nanocrystallization of glass. "Self-limited nanocrystallization of glass can be achieved by taking advantage of the rigid environment of the solid-state matrix, rather than the conventional solution and vapor conditions to modulate the ionic migration kinetics," explained Shifeng Zhou, School of Materials Science and Engineering, South China University of Technology, Guangzhou, China. "It allows us to create glass-ceramics embedded with a CeO2:fluorine (F) nanostructure." The viscous glass matrix involved poses a considerable constraint for oxide (O2-) and F- ion diffusion, so the group gradually etches trifluorocerium (CeF3) by O2- ions within an oxide matrix until F - doped CeO2 is generated in a controllable manner. It's important to note that this technology is also routinely used to prepare other UV absorbers such as zinc oxide (ZnO) and titanium oxide (TiO2). "This work establishes an effective approach for the functionalization of glass," said Zhou. "And it allowed us to demonstrate the construction of a novel glass-based UV absorber." The group's innovative approach for fabricating the UV absorber has important implications "for the construction of novel glass materials with new functions via microstructure engineering," he added. Among the group's key discoveries was finding that the self-limited nanocrystallinization of glass is indeed an effective way to functionalize it. The special glass they created suppresses photocatalytic and catalytic activity, while boasting an extremely high UV-absorbing capacity. "Our glass shows excellent optical quality, and it can be easily fabricated either in bulk form or as a film," said Zhou. "It effectively protects organic dye and living cells from UV radiation damage." Potential applications for the group's work include radiation hardening of electronic devices, serving as a biological shield, and preserving cultural artifacts and relics. "In space, the high-energy radiation environment encountered by electronic equipment aboard spacecraft can be quite damaging," noted Zhou. "Fortunately, in the future, if you add a radiation-blocking coating onto the surface of the package - a transparent glass/polymer material - the device would be well protected, and its service lifetime may be prolonged." In terms of applications as biological shields and to preserve cultural artifacts and relics, the special glass can "protect cells from UV-induced damage," he added. Going forward, the group plans to focus their efforts on developing other novel and effective glass-based UV absorbers, using the self-limited nanocrystallization method. "We'll explore ways for large-scale fabrication of this type of film, which is extremely important for practical applications," said Zhou. "Our group will also further study the functionalization of glass based on its microstructure engineering, because we believe this fundamental research may have great significance for the glass industry." Science Paper: Glass composite as robust UV absorber for biological protection
Related Links The Optical Society Hospital and Medical News at InternDaily.com
|
|
The content herein, unless otherwise known to be public domain, are Copyright 1995-2024 - Space Media Network. All websites are published in Australia and are solely subject to Australian law and governed by Fair Use principals for news reporting and research purposes. AFP, UPI and IANS news wire stories are copyright Agence France-Presse, United Press International and Indo-Asia News Service. ESA news reports are copyright European Space Agency. All NASA sourced material is public domain. Additional copyrights may apply in whole or part to other bona fide parties. All articles labeled "by Staff Writers" include reports supplied to Space Media Network by industry news wires, PR agencies, corporate press officers and the like. Such articles are individually curated and edited by Space Media Network staff on the basis of the report's information value to our industry and professional readership. Advertising does not imply endorsement, agreement or approval of any opinions, statements or information provided by Space Media Network on any Web page published or hosted by Space Media Network. General Data Protection Regulation (GDPR) Statement Our advertisers use various cookies and the like to deliver the best ad banner available at one time. All network advertising suppliers have GDPR policies (Legitimate Interest) that conform with EU regulations for data collection. By using our websites you consent to cookie based advertising. If you do not agree with this then you must stop using the websites from May 25, 2018. Privacy Statement. Additional information can be found here at About Us. |