Fuel cells and water electrolyzers that are cheap and efficient will form the cornerstone of a hydrogen fuel based economy, which is one of the most promising clean and sustainable alternatives to fossil fuels. These devices rely on materials called electrocatalysts to work, so the development of efficient and low-cost catalysts is essential to make hydrogen fuel a viable alternative. Researchers at Aalto university have developed a new catalyst material to improve these technologies.

The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are the most important electrochemical reactions that limit the efficiencies of hydrogen fuel cells (for powering vehicles and power generation), water electrolyzers (for clean hydrogen production), and high-capacity metal-air batteries. Physicists and chemists at Aalto collaborating with researchers at CNRS France, and Vienna in Austria have developed a new catalyst that drive these reactions more efficiently than other bifunctional catalysts currently available.

The researchers also found that the electrocatalytic activity of their new catalyst can be significantly altered depending on choice of the material on which the catalyst was deposited.

"We want to replace traditional expesive and scarce catalysts based on precious metals like platinum and iridium with highly active and stable alternatives composed of cheap and earth-abundant elements such as transition metals, carbon and nitrogen." says Dr Mohammad Tavakkoli, the researcher at Aalto who led the work and wrote the paper.

In collaboration with CNRS the team produced a highly porous graphene-carbon nanotube hybrid and doped it with single atoms of other elements known to make good catalysts. Graphene and carbon nanotube (CNT) are the one atom thick two- and one dimensional allotropes of carbon, respectively, which have attracted tremendous interest in both academia and industry due to their outstanding properties compared more traditional materials.

They developed an easy and scalable method to grow these nanomaterials at the same time, combining their properties in a single product. "We are one of the leading teams in the world for the scalable synthesis of double-walled carbon nanotubes. The innovation here was to modify our fabrication process to prepare these unique samples," said Dr Emmanuel Flahut, research director at CNRS.

In this one-step process, they could also dope the graphene with nitrogen and/or metallic (Cobalt and Molybdenum) single-atoms as a promising strategy to produce single-atom catalysts (SACs). In catalysis science, the new field of SACs with isolated metal atoms dispersed on solid supports has attracted wide research attention because of the maximum atom-utilization efficiency and the unique properties of SACs. Compared with rival strategies for making SACs, the method used by the Aalto and CNRS team provides an easy method which takes place in one step, keeping costs down.

Catalysts are usually deposited on an underlying substrate. The role this substrate plays on the final reactivity of the catalyst is usually neglected by researchers, however for this new catalyst, the researchers spotted the substrate played an important part in its efficiency.

The team found porous structure of their material allows to access more active catalyst sites formed at its interface with the substrate, so they developed a new microscopy analysis method to measure how this interface could be altered to produce the most effective catalyst.

They hope their study of substrate effects on the catalytic activity of porous materials establishes a basis for the rational design of high-performance electrodes for the electrochemical energy devices and provides guidelines for future studies.

Research paper

Related Links
Aalto University
All About Oil and Gas News at OilGasDaily.com

Tweet

Thanks for being here; We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain. With the rise of Ad Blockers, and Facebook - our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don't have a paywall - with those annoying usernames and passwords. Our news coverage takes time and effort to publish 365 days a year. If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.
SpaceDaily Contributor $5 Billed Once credit card or paypal		SpaceDaily Monthly Supporter $5 Billed Monthly paypal only

Perfect storm of coronavirus, oil price war may cause world to run out of storage capacity
London, UK (Sputnik) Mar 19, 2020
OPEC+'s failure to come to a consensus on possible oil supply cuts amid the global economic slowdown expected due to COVID-19 has sent oil futures tumbling, with the OPEC basket trading for $30.63 on Tuesday, down by more than 40 percent since early March, and as much as 55 percent since January. Both onshore and offshore oil storage facilities may run out of spare capacity in the next six months thanks to rock-bottom prices due to falling economic activity and the Saudi-Russian dispute on supply ... read more